Comparison of the extraction performances of three different mitochondria enrichment protocols (differential centrifugation, sucrose gradient, a commercial kit based on surfactants) on ten different cell lines. Samples were analysed on several instrumental platforms.
Mitochondrial pellets were lysed in RapiGest 0.1% (RG, Waters Corporation) and digested with trypsin in 50 mM ammonium bicarbonate. Before digestion the proteins were first quantified according to the Bradford assay and then reduced with 1 mM TCEP 50 mM and alkylated wit IAA 20 mM. Peptides were recovered by centrifugation and then loaded directly on the respective chromatographic system for the mass spectrometry analysis or on a SDS-PAGE for WB analysis.
Raw data were processed with PEAKS 7.5 with the following search parameters.
Parent Mass Error Tolerance - depending on the instrument - 10.0 to 40 ppm
Fragment Mass Error Tolerance - depending on the instrument - 0.05 to 0.6 Da
Enzyme specificity Trypsin
Max Missed Cleavages: 2
Non-specific Cleavage: 1
Fixed Modifications: Carbamidomethylation (C)
Variable Modifications: Oxidation (M), Deamidation (NQ)
Max variable PTM per peptide: 2
The searched database was downloaded from www.nextprot.org and contained the latest annotated human proteome including isoforms (42,151 entries).